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Restoring Alkalinity to the Ocean



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04-12-2024 08:09
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
<--- Click on "sealover" (to the left of the arrow)
...deleted spam and whining...

Stop spamming. Stop whining.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
04-12-2024 08:46
Im a BM
★★★★☆
(1622)
sealover wrote:
IBdaMann wrote:
sealover wrote:
[quote]IBdaMann wrote:
To a scientist:

pH is a real number: 0 < pH < 14 ; pH = -ln[H+]

To a software engineer:

double pH (double molarHydronium) {
return -Math.log(molarHydronium);
}


Aren't you any good at math? Can't you calculate the pH of a 1.5 N nitric acid solution?

Hey Bozo, I put the Java code right there in my response. Didn't you run it? I get an answer of -0.4054651081081644

Run the code, dipsh't.



I THOUGHT IT WAS MY DYSLEXIA ACTING UP

And I never bothered to do the calculation myself.

So tonight, when I was looking up values for the less-than-zero pH of some concentrated strong acids...

I realized it CAN'T be right. No way was 1.5 N nitric acid going to have pH THAT far below zero. If 5 N nitric acid had pH = -0.7, then 1.5 N nitric acid couldn't possibly have pH = -0.41. It was just too low to make sense.

I finally looked for the source of the MATH ERROR.

There really IS a GLARING MATH ERROR!

The DEFINITION FOR pH GIVEN BY IBdaMann is WRONG.

His definition (top of page) is "pH = -ln[H+]"

-ln[H+] is NOT the negative logarithm (base 10) of H+ concentration.

-ln[H+] is the negative NATURAL LOG (base "e") of H+ concentration.


THE CORRECT DEFINITION OF pH

pH = -log[H+]

-log[H+] is the negative logarithm (base 10)



IBdaMann's code did correctly calculate the negative NATURAL LOG (ln) of H+ concentration in a 1.5 N solution of nitric acid. = -0.41

I FINALLY did the math MYSELF tonight to calculate 1.5 N nitric acid pH.

The answer: pH = -0.176

There is an important distinction between natural logs (ln) and logarithms (log).

So, having established that the pH of a 1.5 N nitric acid solution is -0.176

I can predict that the pH of a 1.5 N sodium hydroxide solution is 14.176


Yes, indeed, there was a HUGE math error in the way IBdaMann's code calculated pH, using natural logs instead of logarithms of base 10.

Edited on 04-12-2024 08:54
04-12-2024 17:45
Im a BM
★★★★☆
(1622)
<--- Click on "sealover" (to the left of the arrow)

It will open the "sealover" profile page. The "Last 10 posts:" shows ten biogeochemistry related threads. Any of them can be opened with a click. The first post on page 1 of this thread is by "sealover" to open profile page.

------------------------------------------------------------------------

sealover wrote:
IBdaMann wrote:
sealover wrote:
IBdaMann wrote:
To a scientist:

pH is a real number: 0 < pH < 14 ; pH = -ln[H+]

To a software engineer:

double pH (double molarHydronium) {
return -Math.log(molarHydronium);
}


Aren't you any good at math? Can't you calculate the pH of a 1.5 N nitric acid solution?

Hey Bozo, I put the Java code right there in my response. Didn't you run it? I get an answer of -0.4054651081081644

Run the code, dipsh't.



I THOUGHT IT WAS MY DYSLEXIA ACTING UP

And I never bothered to do the calculation myself.

So tonight, when I was looking up values for the less-than-zero pH of some concentrated strong acids...

And this is SO embarrassing...

I realized it CAN'T be right. No way was 1.5 N nitric acid going to have pH THAT far below zero. If 5 N nitric acid had pH = -0.7, then 1.5 N nitric acid couldn't POSSIBLY have pH = -0.41. It was just too low to make mathematical sense.

I finally looked for the source of the MATH ERROR.

There really IS a GLARING MATH ERROR!

The DEFINITION FOR pH GIVEN BY IBdaMann is WRONG.

His definition (top of page) is "pH = -ln[H+]"

-ln[H+] is NOT the negative logarithm (base 10) of H+ concentration.

-ln[H+] is the negative NATURAL LOG (base "e") of H+ concentration.


THE CORRECT DEFINITION OF pH

pH = -log[H+]

-log[H+] is the negative logarithm (base 10)

I feel very foolish that I didn't notice the error long before I copied the result so many times. I even used the incorrect result to predict that a 1.5 N solution of sodium hydroxide would have pH = 14.405461... Again, without actually checking the math myself. Big mistake as a scientist.

IBdaMann's code did correctly calculate the negative NATURAL LOG (ln) of H+ concentration in a 1.5 N solution of nitric acid. = -0.4054651...

I FINALLY did the math MYSELF tonight to calculate 1.5 N nitric acid pH.

The answer: pH = -0.176

There is an important distinction between natural logs (ln) and logarithms (log).

So, having established that the pH of a 1.5 N nitric acid solution is -0.176

I can predict that the pH of a 1.5 N sodium hydroxide solution is 14.176

Yes, there was a HUGE math error in the way IBdaMann's code calculated pH, using natural logs instead of logarithms of base 10.


But I should have run the numbers myself before I blindly copied them.

I should have known that IBdaMann wasn't using the right math for pH.
04-12-2024 19:46
SwanProfile picture★★★★★
(6002)
Im a BM wrote:
IBdaMann wrote:
Im a BM wrote: And you can't EVER admit when you are WRONG.

You can never admit when my code is correct.


I never tested your "code" to see if it was correct. No way was I going to open up a link posted by a scientifically illiterate troll.

I didn't even finally open ANY of your links until a few months back when I read your ABSURD thing about "Debunking ocean acidification".

The answer of pH -0.40+ was correct. If you used your "code" to get it, then YOUR CODE IS CORRECT!

However, the answer of pH -0.40+ CONTRADICTS your earlier claims, including in the very same post when you insisted that pH must be greater than zero.

Yes, the "magical" acid you invoked while "debunking" my claim that a drop of acid added to pure water would cause a huge decrease in pH.

NO! The effect on SEA WATER would be "more pronounced."

And you could have explained it as because of the IMPURITIES in sea water that diminish the buffering power of the water itself. Water itself is a powerful buffer, right? But it's buffering power is diluted by impurities such as bicarbonate ions, in sea water. So the impact of a drop of acid will be "more pronounced".

Because you were NEVER WRONG about ANY of it.

And I deserve to be mocked as "Mr. Chemistry Genius" because I'm here PRETENDING TO BE A CHEMIST! And that is a despicable thing to do.


Licking stamps does not make you a chemist


IBdaMann claims that Gold is a molecule, and that the last ice age never happened because I was not there to see it. The only conclusion that can be drawn from this is that IBdaMann is clearly not using enough LSD.

According to CDC/Government info, people who were vaccinated are now DYING at a higher rate than non-vaccinated people, which exposes the covid vaccines as the poison that they are, this is now fully confirmed by the terrorist CDC

This place is quieter than the FBI commenting on the chink bank account information on Hunter Xiden's laptop

I LOVE TRUMP BECAUSE HE PISSES OFF ALL THE PEOPLE THAT I CAN'T STAND.

ULTRA MAGA

"Being unwanted, unloved, uncared for, forgotten by everybody, I think that is a much greater hunger, a much greater poverty than the person who has nothing to eat." MOTHER THERESA OF CALCUTTA

So why is helping to hide the murder of an American president patriotic?


Sonia makes me so proud to be a dumb white boy


Now be honest, was I correct or was I correct? LOL
04-12-2024 20:12
Im a BM
★★★★☆
(1622)
Swan wrote:
Im a BM wrote:
IBdaMann wrote:
Im a BM wrote: And you can't EVER admit when you are WRONG.

You can never admit when my code is correct.


I never tested your "code" to see if it was correct. No way was I going to open up a link posted by a scientifically illiterate troll.

I didn't even finally open ANY of your links until a few months back when I read your ABSURD thing about "Debunking ocean acidification".

The answer of pH -0.40+ was correct. If you used your "code" to get it, then YOUR CODE IS CORRECT!

However, the answer of pH -0.40+ CONTRADICTS your earlier claims, including in the very same post when you insisted that pH must be greater than zero.

Yes, the "magical" acid you invoked while "debunking" my claim that a drop of acid added to pure water would cause a huge decrease in pH.

NO! The effect on SEA WATER would be "more pronounced."

And you could have explained it as because of the IMPURITIES in sea water that diminish the buffering power of the water itself. Water itself is a powerful buffer, right? But it's buffering power is diluted by impurities such as bicarbonate ions, in sea water. So the impact of a drop of acid will be "more pronounced".

Because you were NEVER WRONG about ANY of it.

And I deserve to be mocked as "Mr. Chemistry Genius" because I'm here PRETENDING TO BE A CHEMIST! And that is a despicable thing to do.


Licking stamps does not make you a chemist

I was unambiguously WRONG in this case. I claimed, incorrectly, that the answer given by IBdaMann's code was CORRECT, with pH = -0.41 for a solution of 1.5 N nitric acid. I falsely claimed that this validated the "code". Well, the only thing "correct" about the code's answer was that the pH is BELOW ZERO.

I would be even more embarrassed if this were one of the posts where I PRETENDED to have double checked the math "with pen and paper".

I finally DID "test the 'code' to see if it was correct".

No, the "code" is NOT correct.

It does NOT calculate pH correctly.

IBdaMann's "code" gave pH = -0.40.. for 1.5 N nitric acid. NOT CORRECT.

The problem with the code is that is uses NATURAL LOG (ln) rather than the LOGARITHM (log). Logarithm (log) is base 10. Natural Log (ln) is base "e".

SO, when IBdaMann set up the code with pH = -ln[H+], it was WRONG.

The correct formula is pH = -log[H+]

Using the CORRECT formula applied to 1.5 N nitric acid, pH = -0.176
05-12-2024 15:29
SwanProfile picture★★★★★
(6002)
Im a BM wrote:
Swan wrote:
Im a BM wrote:
IBdaMann wrote:
Im a BM wrote: And you can't EVER admit when you are WRONG.

You can never admit when my code is correct.


I never tested your "code" to see if it was correct. No way was I going to open up a link posted by a scientifically illiterate troll.

I didn't even finally open ANY of your links until a few months back when I read your ABSURD thing about "Debunking ocean acidification".

The answer of pH -0.40+ was correct. If you used your "code" to get it, then YOUR CODE IS CORRECT!

However, the answer of pH -0.40+ CONTRADICTS your earlier claims, including in the very same post when you insisted that pH must be greater than zero.

Yes, the "magical" acid you invoked while "debunking" my claim that a drop of acid added to pure water would cause a huge decrease in pH.

NO! The effect on SEA WATER would be "more pronounced."

And you could have explained it as because of the IMPURITIES in sea water that diminish the buffering power of the water itself. Water itself is a powerful buffer, right? But it's buffering power is diluted by impurities such as bicarbonate ions, in sea water. So the impact of a drop of acid will be "more pronounced".

Because you were NEVER WRONG about ANY of it.

And I deserve to be mocked as "Mr. Chemistry Genius" because I'm here PRETENDING TO BE A CHEMIST! And that is a despicable thing to do.


Licking stamps does not make you a chemist

I was unambiguously WRONG in this case. I claimed, incorrectly, that the answer given by IBdaMann's code was CORRECT, with pH = -0.41 for a solution of 1.5 N nitric acid. I falsely claimed that this validated the "code". Well, the only thing "correct" about the code's answer was that the pH is BELOW ZERO.

I would be even more embarrassed if this were one of the posts where I PRETENDED to have double checked the math "with pen and paper".

I finally DID "test the 'code' to see if it was correct".

No, the "code" is NOT correct.

It does NOT calculate pH correctly.

IBdaMann's "code" gave pH = -0.40.. for 1.5 N nitric acid. NOT CORRECT.

The problem with the code is that is uses NATURAL LOG (ln) rather than the LOGARITHM (log). Logarithm (log) is base 10. Natural Log (ln) is base "e".

SO, when IBdaMann set up the code with pH = -ln[H+], it was WRONG.

The correct formula is pH = -log[H+]

Using the CORRECT formula applied to 1.5 N nitric acid, pH = -0.176


Your code is a crummy Ovaltine commercial




IBdaMann claims that Gold is a molecule, and that the last ice age never happened because I was not there to see it. The only conclusion that can be drawn from this is that IBdaMann is clearly not using enough LSD.

According to CDC/Government info, people who were vaccinated are now DYING at a higher rate than non-vaccinated people, which exposes the covid vaccines as the poison that they are, this is now fully confirmed by the terrorist CDC

This place is quieter than the FBI commenting on the chink bank account information on Hunter Xiden's laptop

I LOVE TRUMP BECAUSE HE PISSES OFF ALL THE PEOPLE THAT I CAN'T STAND.

ULTRA MAGA

"Being unwanted, unloved, uncared for, forgotten by everybody, I think that is a much greater hunger, a much greater poverty than the person who has nothing to eat." MOTHER THERESA OF CALCUTTA

So why is helping to hide the murder of an American president patriotic?


Sonia makes me so proud to be a dumb white boy


Now be honest, was I correct or was I correct? LOL
05-12-2024 18:38
Im a BM
★★★★☆
(1622)
<--- Click on "sealover" (to the left of the arrow)

This will open the "sealover" profile page. The "Last 10 posts:" shows ten biogeochemistry related threads. Any of them can be opened with a click. The first post on page 1 of this thread is by "sealover", to open profile page.

-----------------------------------------------------------
This thread really IS about the biogeochemistry of restoring alkalinity to the ocean, primarily through the action of sulfate reducing bacteria. As an example, a methane oxidizing sulfate reducing bacteria, under low oxygen conditions:

CH4 + SO4(2-) = H20 + H2S + CO3(2-)
Methane + sulfate = water + hydrogen sulfide + carbonate

versus

CH4 + 2O2 = 2H2O + CO2 for aerobic respiration or combustion
Methane + oxygen = water + carbon dioxide


IBdaMann wrote:
sealover wrote:Yes you can reduce a sulfate.

Why don't you just define what you mean by "reduce a sulphate" . Maybe you both actually agree.

Google "defining one's terms"



March 12, 2022, just a couple of days after my first post.

Into the Night was insisting "You cannot reduce a sulfate".

Sulfate reduction by bacteria under low oxygen conditions is a very important biochemical process in nature.

In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Aerobic respiration or combustion transforms organic carbon into carbon dioxide. Methane, for example:

CH4 + 2O2 = 2H2O + CO2

Microbial sulfate reduction transforms organic carbon into carbonate and bicarbonate ion. Methane, for example:

CH4 + SO4(2-) = H2O + H2S + CO3(2-) or HCO3-
methane + sulfate ion = water + hydrogen sulfide + carbonate ion, bicarbonate

Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

This thread includes scientific discussion of the biogeochemistry of alkalinity generation in coastal wetlands by microbial sulfate reduction.

Entering the sea primarily as submarine groundwater discharge, the carbonate ions and bicarbonate ions produced by sulfate reduction are a counterbalance to the carbonic acid entering the sea from the atmosphere.

Note, this was just two days in, and Into the Night is insisting that SULFATE CANNOT BE REDUCED, already with the parrot-like repetition of the same short sentence over and over and over.

And that was the ENTIRE ARGUMENT. The entire chemical explanation for why sulfate cannot be reduced was the four word claim that it cannot.

Okay, in steps IBdaMann. Again, just two days after we met,

"Why don't you just define what you mean by 'reduce a sulphate'. Maybe you both actually agree. Google 'defining one's terms'."


Well, one thing I notice is that he spells sulfate as "sulphate".

So I know he did NOT study chemistry in the United States. His familiarity with the term "sulfate" was to use the British spelling. He hadn't communicated chemistry enough with US chemists to have gotten used to the American spelling of sulfate. Hadn't seen the term on the blackboard/whiteboard of an American chemistry classroom. Wherever he might have studied chemistry, it wasn't the US.

But, IBdaMann thinks its possible that Into the Night and I might agree, if we just play some kind of definition word game.

Either sulfate can be reduced or it cannot.

I have been in literally thousands of discussions with chemists - the kind with chemistry degrees from universities.

Nobody gets to come in and define their own terms. Nobody gets to have their own personal definition for sulfate reduction. Nobody has to define "sulfate reduction" every time they use the term.

Well, two and a half years later...

Good old Into the Night, chemistry genius, still says that sulfate cannot be reduced. Still making up rules for chemistry, like the one about how pH is not ALLOWED to be less than or equal to zero. Still repeating one short sentence over and over and over.. Then RQAA because he ALREADY repeated that sentence..

But, IBdaMann didn't use the term "sulphate" because he actually ever studied chemistry somewhere, and it was not the United States. He wasn't accustomed to the British spelling because he usually wrote for British chemists.

IBdaMann had so LITTLE knowledge of chemistry, he hadn't seen or used the word "sulfate" often enough with its American spelling to know it.

And he had so LITTLE knowledge of chemistry, he didn't know to immediately respond to Into the Night's absurd unsupported contrarian assertion prohibiting sulfate reduction as something that defies science.

Of course, sulfate CAN be reduced by sulfate reducing bacteria..

IBdaMann encouraged me to:

"Google 'defining one's terms'"

Apparently, Google is a place IBdaMann recommends as a reliable source of information.

Google: Microbial sulfate reduction

If you studied any chemistry, you know what I mean by "reduce a sulphate".

It's kind of pathetic if you really need me to define it for you.

Even if you DIDN'T study chemistry and don't already know it, Google "sulfate reduction" before you insist that it is MY responsibility to teach you the meaning of the scientific terms that all the other scientists use.

It makes it impossible to even discuss it in any meaningful way.

In all this time, I still haven't really acquired any fondness for trolls.
Edited on 05-12-2024 19:32
06-12-2024 00:12
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
Swan wrote:
Im a BM wrote:
[quote]IBdaMann wrote:
[quote]Im a BM wrote: And you can't EVER admit when you are WRONG.

You can never admit when my code is correct.


I never tested your "code" to see if it was correct. No way was I going to open up a link posted by a scientifically illiterate troll.

Stop spamming.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
06-12-2024 00:30
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
This thread really IS about the biogeochemistry

No such thing.
Im a BM wrote:
of restoring alkalinity to the ocean,

Alkalinity is not a chemical.
Im a BM wrote:
primarily through the action of sulfate reducing bacteria.

You cannot reduce sulfate. Sulfate is not a chemical.
Im a BM wrote:
As an example, a methane oxidizing sulfate reducing bacteria,

Sulfate is not a chemical.
Im a BM wrote:
Sulfate reduction by bacteria

Sulfate is not a chemical.
Im a BM wrote:
is a very important biochemical process in nature.

No such thing as 'biogeochemcal'.
Im a BM wrote:
In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Sulfate is not a chemical. Carbon is not organic.
Im a BM wrote:
Aerobic respiration or combustion transforms organic carbon into carbon dioxide. Methane, for example:

Carbon is not organic. Carbon is not carbon dioxide or methane.
Im a BM wrote:
Microbial sulfate reduction

Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
transforms organic carbon

Carbon is not organic.
Im a BM wrote:
into carbonate and bicarbonate ion.

Carbonate is not a chemical. Bicarbonate is not a chemical.
Im a BM wrote:
Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

Carbonate is not a chemical. Bicarbonate is not a chemical. Sulfate is not a chemical. Alkalinity is not a chemical. There is no such thing as a 'marine ecosystem'. Buzzword fallacies.
Im a BM wrote:
This thread includes scientific discussion

You are not discussing any science. You deny science.
Im a BM wrote:
of the biogeochemistry

No such thing.
Im a BM wrote:
of alkalinity generation

Alkalinity is not a chemical.
Im a BM wrote:
in coastal wetlands by microbial sulfate reduction.

Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
the carbonate ions and bicarbonate ions produced by sulfate reduction

Carbonate is not a chemical. Bicarbonate is not a chemical. Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
are a counterbalance to the carbonic acid entering the sea from the atmosphere.

The atmosphere is not carbonic acid.
Im a BM wrote:
So I know he did NOT study chemistry in the United States. His familiarity with the term "sulfate" was to use the British spelling.

Sulfate is not a chemical.
Im a BM wrote:
He hadn't communicated chemistry enough with US chemists to have gotten used to the American spelling of sulfate.

Sulfate is not a chemical.
Im a BM wrote:
Either sulfate can be reduced or it cannot.

It cannot. Sulfate is not a chemical.
Im a BM wrote:
I have been in literally thousands of discussions with chemists - the kind with chemistry degrees from universities.

Chemistry does not use consensus. Science does not use consensus. Science is not a degree, title, university, college, or government agency.
Im a BM wrote:
Nobody gets to come in and define their own terms.

You are not defining anything. You are just throwing out massive amounts of buzzwords.
Im a BM wrote:
Nobody gets to have their own personal definition for sulfate reduction.

Sulfate is not a chemical. Sulfate cannot be reduced.
Im a BM wrote:
Nobody has to define "sulfate reduction" every time they use the term.

Sulfate is not a chemical. Sulfate cannot be reduced.
Im a BM wrote:
Well, two and a half years later...

Still making up rules for chemistry,

You deny chemistry. You are no chemist.
Im a BM wrote:
like the one about how pH is not ALLOWED to be less than or equal to zero.

I already know you have no understanding of pH.
Im a BM wrote:
Still repeating one short sentence over and over and over..

You keep spamming the same thing. Stop spamming.
Im a BM wrote:
Then RQAA because he ALREADY repeated that sentence..

Redefinition fallacy.
Im a BM wrote:
But, IBdaMann didn't use the term "sulphate" because he actually ever studied chemistry somewhere, and it was not the United States. He wasn't accustomed to the British spelling because he usually wrote for British chemists.

Sulphate is not a chemical.
Im a BM wrote:
IBdaMann had so LITTLE knowledge of chemistry, he hadn't seen or used the word "sulfate" often enough with its American spelling to know it.

Sulfate is not a chemical.
Im a BM wrote:
And he had so LITTLE knowledge of chemistry, he didn't know to immediately respond to Into the Night's absurd unsupported contrarian assertion prohibiting sulfate reduction as something that defies science.

Sulfate cannot be reduced. Sulfate is not a chemical.
Im a BM wrote:
Of course, sulfate CAN be reduced by sulfate reducing bacteria..

No such thing. Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
IBdaMann encouraged me to:

"Google 'defining one's terms'"

Apparently, Google is a place IBdaMann recommends as a reliable source of information.

Google: Microbial sulfate reduction

If you studied any chemistry, you know what I mean by "reduce a sulphate".

Sulphate is not a chemical. It cannot be reduced. Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
It's kind of pathetic if you really need me to define it for you.

Even if you DIDN'T study chemistry and don't already know it, Google "sulfate reduction" before you insist that it is MY responsibility to teach you the meaning of the scientific terms that all the other scientists use.

Chemistry isn't Google. Science isn't Google.
Im a BM wrote:
It makes it impossible to even discuss it in any meaningful way.

In all this time, I still haven't really acquired any fondness for trolls.

Mantra 1a. Lame.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
06-12-2024 05:04
Im a BM
★★★★☆
(1622)
Im a BM wrote:
<--- Click on "sealover" (to the left of the arrow)

This will open the "sealover" profile page. The "Last 10 posts:" shows ten biogeochemistry related threads. Any of them can be opened with a click. The first post on page 1 of this thread is by "sealover", to open profile page.

-----------------------------------------------------------
This thread really IS about the biogeochemistry of restoring alkalinity to the ocean, primarily through the action of sulfate reducing bacteria. As an example, a methane oxidizing sulfate reducing bacteria, under low oxygen conditions:

CH4 + SO4(2-) = H20 + H2S + CO3(2-)
Methane + sulfate = water + hydrogen sulfide + carbonate

versus

CH4 + 2O2 = 2H2O + CO2 for aerobic respiration or combustion
Methane + oxygen = water + carbon dioxide

Just for fun and laughs, bring in the CHEMISTRY CLOWN!

The Chemistry Clown says that sulfate cannot be chemically reduced, and there is not even any such thing as organic carbon.

The Chemistry Clown says "pH cannot be equal to or below zero."

Reality check:

pH = -log[H+] = negative logarithm of hydrogen ion Normality, moles per liter

Sour apple juice, pH 3, has [H+] concentration at 10 to the minus 3 power.

Apple juice with hydrogen ion concentration at 0.001 N

Apple juice is a dilute acid with pH above zero.

Because the logarithm of apple juice hydrogen ion concentration is NEGATIVE, at 10 to the NEGATIVE 3 power, its NEGATIVE logarithm HAS TO BE POSITIVE.

So its pH is POSITIVE because the logarithm of [H+] is NEGATIVE.

Okay, that also means that if the logarithm of [H+] is POSITIVE, then its NEGATIVE logarithm (i.e. pH) HAS TO BE NEGATIVE.

Right on the border line... a 1 N solution of HCl, hydrochloric acid.

pH = -log[H+] = -log[1 N] = 0 = pH zero, exactly.



dolijg'pa pgujq'og
;,ngpoi][q


IBdaMann wrote:
sealover wrote:Yes you can reduce a sulfate.

Why don't you just define what you mean by "reduce a sulphate" . Maybe you both actually agree.

Google "defining one's terms"



March 12, 2022, just a couple of days after my first post.

Into the Night was insisting "You cannot reduce a sulfate".

Sulfate reduction by bacteria under low oxygen conditions is a very important biochemical process in nature.

In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Aerobic respiration or combustion transforms organic carbon into carbon dioxide. Methane, for example:

CH4 + 2O2 = 2H2O + CO2

Microbial sulfate reduction transforms organic carbon into carbonate and bicarbonate ion. Methane, for example:

CH4 + SO4(2-) = H2O + H2S + CO3(2-) or HCO3-
methane + sulfate ion = water + hydrogen sulfide + carbonate ion, bicarbonate

Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

This thread includes scientific discussion of the biogeochemistry of alkalinity generation in coastal wetlands by microbial sulfate reduction.

Entering the sea primarily as submarine groundwater discharge, the carbonate ions and bicarbonate ions produced by sulfate reduction are a counterbalance to the carbonic acid entering the sea from the atmosphere.

Note, this was just two days in, and Into the Night is insisting that SULFATE CANNOT BE REDUCED, already with the parrot-like repetition of the same short sentence over and over and over.

And that was the ENTIRE ARGUMENT. The entire chemical explanation for why sulfate cannot be reduced was the four word claim that it cannot.

Okay, in steps IBdaMann. Again, just two days after we met,

"Why don't you just define what you mean by 'reduce a sulphate'. Maybe you both actually agree. Google 'defining one's terms'."


Well, one thing I notice is that he spells sulfate as "sulphate".

So I know he did NOT study chemistry in the United States. His familiarity with the term "sulfate" was to use the British spelling. He hadn't communicated chemistry enough with US chemists to have gotten used to the American spelling of sulfate. Hadn't seen the term on the blackboard/whiteboard of an American chemistry classroom. Wherever he might have studied chemistry, it wasn't the US.

But, IBdaMann thinks its possible that Into the Night and I might agree, if we just play some kind of definition word game.

Either sulfate can be reduced or it cannot.

I have been in literally thousands of discussions with chemists - the kind with chemistry degrees from universities.

Nobody gets to come in and define their own terms. Nobody gets to have their own personal definition for sulfate reduction. Nobody has to define "sulfate reduction" every time they use the term.

Well, two and a half years later...

Good old Into the Night, chemistry genius, still says that sulfate cannot be reduced. Still making up rules for chemistry, like the one about how pH is not ALLOWED to be less than or equal to zero. Still repeating one short sentence over and over and over.. Then RQAA because he ALREADY repeated that sentence..

But, IBdaMann didn't use the term "sulphate" because he actually ever studied chemistry somewhere, and it was not the United States. He wasn't accustomed to the British spelling because he usually wrote for British chemists.

IBdaMann had so LITTLE knowledge of chemistry, he hadn't seen or used the word "sulfate" often enough with its American spelling to know it.

And he had so LITTLE knowledge of chemistry, he didn't know to immediately respond to Into the Night's absurd unsupported contrarian assertion prohibiting sulfate reduction as something that defies science.

Of course, sulfate CAN be reduced by sulfate reducing bacteria..

IBdaMann encouraged me to:

"Google 'defining one's terms'"

Apparently, Google is a place IBdaMann recommends as a reliable source of information.

Google: Microbial sulfate reduction

If you studied any chemistry, you know what I mean by "reduce a sulphate".

It's kind of pathetic if you really need me to define it for you.

Even if you DIDN'T study chemistry and don't already know it, Google "sulfate reduction" before you insist that it is MY responsibility to teach you the meaning of the scientific terms that all the other scientists use.

It makes it impossible to even discuss it in any meaningful way.

In all this time, I still haven't really acquired any fondness for trolls.
06-12-2024 10:23
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
<--- Click on "sealover" (to the left of the arrow)

Stop spamming.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
07-12-2024 06:53
Im a BM
★★★★☆
(1622)
The birth of a respectful and productive discussion about ocean acidification.

From March 10, 2022 - Within hours of very first "sealover" post.

The assertions that "sealover" made regarding sea water chemistry were immediately challenged.

My stupidity for suggesting that a liter of pure water, with virtually no pH buffering capacity (i.e. alkalinity), would show a much greater pH decrease upon addition of a drop of acid, compared to a liter of sea water, was mocked.

No, that was NOT the answer, says IBdaMann, most respectfully.

The CORRECT answer is that:

"The impact of a drop of acid would be more pronounced on the sea water than on the pure water." - IBdaMann


So, within hours of my first post, in March 2022, the first "debate" about a chemistry point of fact.

Well, this should be easy to clear up, you would think.

OF COURSE sea water is more buffered against pH change than pure water.

That's easy enough to prove to any scientifically literate rational adult, right?

Well, it turns out that it's NOT so easy to prove such a simple point of science to a scientifically illiterate troll.

Two and a half years later, the rebuttal to this first "Mr. Chemistry Genius" claim I made about pure water having virtually no pH buffering capacity CONTINUES.

NO! NO! NO! Water itself is a buffer for acid, they continue to say.

And don't forget that an acid would have to be "magical" to have pH equal zero.

Didn't really get to take the biogeochemistry to very sophisticated level in this particular discussion.

Still can't agree what a buffer is or even how pH works.

Sigh.

IBdaMann wrote:
sealover wrote:If I take a liter of pure water and add just one drop of concentrated acid, I will see a huge drop in pH.

So, Mr. Chemistry Genius, the correct answer is that if you were to get your hands on some magical acid whose pH is 0.0, and you were to add one single drop to one liter/litre of pure water (pH 7.0) and one single drop to one liter/litre of sea water (pH 8.4), the impact of a drop of the acid would be more pronounced on the sea water than on the pure water.

Do the math.

sealover wrote: Remember, this thread is about restoring "alkalinity" to the sea.

That's like restoring white to snow. It's already there. Just go out and claim victory!

sealover wrote:Alkalinity is another word for acid neutralizing capacity.

Great circular definition ... and acidity is another word for alkaline neutralizing capacity.

Acidity is the ability to provide a hydrogen ion. Alkalinity is the ability to accept a hydrogen ion.

sealover wrote:The alkalinity of pure water arises entirely from hydroxide ions.

Do you see what I mean? Only a scientifically illiterate moron would refer to the alkalinity of pure water. Next, you'll be talking about the temperature of deep space.

sealover wrote:The overwhelming majority of the alkalinity in sea water arises from bicarbonate and carbonate ions.

Let's not forget hydroxide, silicates and phosphates. They're people too.

sealover wrote:A 30% depletion of the ocean's alkalinity has resulted in only a small decrease in pH.

That's just one number so I can see how you could so easily pull that out of your arsewhole. I think it explains the stink quite nicely.

sealover wrote:On the other hand, it has caused a HUGE change to the bioavailability of carbonate ion.

The "bioavailability"? Don't you mean the "ecolobiquity"? ... or maybe the "presenvironance"?
07-12-2024 10:45
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
The birth of a respectful and productive discussion about ocean acidification.

You can't acidify an alkaline.
Im a BM wrote:
OF COURSE sea water is more buffered against pH change than pure water.

Water is a buffer.
Im a BM wrote:
That's easy enough to prove to any scientifically literate rational adult, right?

Well, it turns out that it's NOT so easy to prove such a simple point of science to a scientifically illiterate troll.

Your denial of science is YOUR problem.
Im a BM wrote:
Two and a half years later, the rebuttal to this first "Mr. Chemistry Genius" claim I made about pure water having virtually no pH buffering capacity CONTINUES.

Water is a buffer.
Im a BM wrote:
NO! NO! NO! Water itself is a buffer for acid, they continue to say.

It is.
Im a BM wrote:
And don't forget that an acid would have to be "magical" to have pH equal zero.

It is not possible to have a pH of zero.
Im a BM wrote:
Didn't really get to take the biogeochemistry to very sophisticated level in this particular discussion.

There is no such thing as 'biogeochemistry'.
Im a BM wrote:
Still can't agree what a buffer is or even how pH works.

Your own illiteracy is YOUR problem. Stop whining.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
07-12-2024 18:06
Im a BM
★★★★☆
(1622)
Into the Night wrote:
Im a BM wrote:
The birth of a respectful and productive discussion about ocean acidification.

You can't acidify an alkaline.
Im a BM wrote:
OF COURSE sea water is more buffered against pH change than pure water.

Water is a buffer.
Im a BM wrote:
That's easy enough to prove to any scientifically literate rational adult, right?

Well, it turns out that it's NOT so easy to prove such a simple point of science to a scientifically illiterate troll.

Your denial of science is YOUR problem.
Im a BM wrote:
Two and a half years later, the rebuttal to this first "Mr. Chemistry Genius" claim I made about pure water having virtually no pH buffering capacity CONTINUES.

Water is a buffer.
Im a BM wrote:
NO! NO! NO! Water itself is a buffer for acid, they continue to say.

It is.
Im a BM wrote:
And don't forget that an acid would have to be "magical" to have pH equal zero.

It is not possible to have a pH of zero.
Im a BM wrote:
Didn't really get to take the biogeochemistry to very sophisticated level in this particular discussion.

There is no such thing as 'biogeochemistry'.
Im a BM wrote:
Still can't agree what a buffer is or even how pH works.

Your own illiteracy is YOUR problem. Stop whining.


Yes, my own illiteracy is MY problem.

"There is no such thing as 'biogeochemistry'"- Into the Night

Tell that to the editors of the journal BIOGEOCHEMISTRY, where my 1998 paper was published (Biogeochemistry, 1998, volume 42, pages 189-220).

Tell that to the universities who offer courses with the title "Biogeochemistry".

And keep telling yourself that "It is not possible to have a pH of zero".

Then tell 1 N HCl what its pH really IS, because everyone thinks its pH = zero.
08-12-2024 06:32
Im a BM
★★★★☆
(1622)
<--- Click on "sealover" (to the left of the arrow)

This will open the "sealover" profile page. The "Last 10 posts:" shows ten biogeochemistry related threads. Any of them can be opened with a click.
The first post on page 1 of this thread is by "sealover", to open profile page.

-----------------------------------------------------------

This thread really IS about the biogeochemistry of restoring alkalinity to the ocean, primarily through the action of sulfate reducing bacteria. As an example, a methane oxidizing sulfate reducing bacteria, under low oxygen conditions:

CH4 + SO4(2-) = H20 + H2S + CO3(2-)
Methane + sulfate = water + hydrogen sulfide + carbonate

versus

CH4 + 2O2 = 2H2O + CO2 for aerobic respiration or combustion
Methane + oxygen = water + carbon dioxide


IBdaMann wrote:
sealover wrote:Yes you can reduce a sulfate.

Why don't you just define what you mean by "reduce a sulphate" . Maybe you both actually agree.

Google "defining one's terms"



March 12, 2022, just a couple of days after my first post.

Into the Night was insisting "You cannot reduce a sulfate".

Sulfate reduction by bacteria under low oxygen conditions is a very important biochemical process in nature.

In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Aerobic respiration or combustion transforms organic carbon into carbon dioxide. Methane, for example:

CH4 + 2O2 = 2H2O + CO2

Microbial sulfate reduction transforms organic carbon into carbonate and bicarbonate ion. Methane, for example:

CH4 + SO4(2-) = H2O + H2S + CO3(2-) or HCO3-
methane + sulfate ion = water + hydrogen sulfide + carbonate ion, bicarbonate

Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

Anthropogenic CO2 emissions have increased the amount of carbon dioxide dissolved in sea water, consequently increasing the concentration of carbonic acid that forms from a fraction of 1% of the dissolved CO2. This carbonic acid is the source of the "acidification" in the term ocean acidification.

Through the pH buffering of the carbonate system in sea water, this increase in acid concentration has caused little change to the pH of the ocean. It has only decreased by about 0.1 pH unit, from about pH 8.3 to pH 8.2.

Of far greater consequence to marine life than the small pH change is the substantial change to the bioavailability of carbonate ion, CO3(2-), to form calcium carbonate shell. Commercial marine aquaculture must now purchase chemical carbonate to add to sea water in order for it to have enough for healthy larval shell development.

This thread includes scientific discussion of the biogeochemistry of alkalinity generation in coastal wetlands by microbial sulfate reduction.

Entering the sea primarily as submarine groundwater discharge, the carbonate ions and bicarbonate ions produced by sulfate reduction are a counterbalance to the carbonic acid entering the sea from the atmosphere.

Note, this was just two days in, and Into the Night is insisting that SULFATE CANNOT BE REDUCED, already with the parrot-like repetition of the same short sentence over and over and over.

And that was the ENTIRE ARGUMENT. The entire chemical explanation for why sulfate cannot be reduced was the four word claim that it cannot.

Okay, in steps IBdaMann. Again, just two days after we met,

"Why don't you just define what you mean by 'reduce a sulphate'. Maybe you both actually agree. Google 'defining one's terms'."


Well, one thing I notice is that he spells sulfate as "sulphate".

So I know he did NOT study chemistry in the United States. His familiarity with the term "sulfate" was to use the British spelling. He hadn't communicated chemistry enough with US chemists to have gotten used to the American spelling of sulfate. Hadn't seen the term on the blackboard/whiteboard of an American chemistry classroom. Wherever he might have studied chemistry, it wasn't the US.

But, IBdaMann thinks its possible that Into the Night and I might agree, if we just play some kind of definition word game.

Either sulfate can be reduced or it cannot.

I have been in literally thousands of discussions with chemists - the kind with chemistry degrees from universities.

Nobody gets to come in and define their own terms. Nobody gets to have their own personal definition for sulfate reduction. Nobody has to define "sulfate reduction" every time they use the term.

Well, two and a half years later...

Good old Into the Night, chemistry genius, still says that sulfate cannot be reduced. Still making up rules for chemistry, like the one about how pH is not ALLOWED to be less than or equal to zero. Still repeating one short sentence over and over and over.. Then RQAA because he ALREADY repeated that sentence..

But, IBdaMann didn't use the term "sulphate" because he actually ever studied chemistry somewhere, and it was not the United States. He wasn't accustomed to the British spelling because he usually wrote for British chemists.

IBdaMann had so LITTLE knowledge of chemistry, he hadn't seen or used the word "sulfate" often enough with its American spelling to know it.

And he had so LITTLE knowledge of chemistry, he didn't know to immediately respond to Into the Night's absurd unsupported contrarian assertion prohibiting sulfate reduction as something that defies science.

Of course, sulfate CAN be reduced by sulfate reducing bacteria..

IBdaMann encouraged me to:

"Google 'defining one's terms'"

Apparently, Google is a place IBdaMann recommends as a reliable source of information.

Google: Microbial sulfate reduction

If you studied any chemistry, you know what I mean by "reduce a sulphate".

It's kind of pathetic if you really need me to define it for you.

Even if you DIDN'T study chemistry and don't already know it, Google "sulfate reduction" before you insist that it is MY responsibility to teach you the meaning of the scientific terms that all the other scientists use.

It makes it impossible to even discuss it in any meaningful way.

I still haven't really acquired any fondness for trolls.
08-12-2024 09:52
Im a BM
★★★★☆
(1622)
<--- Click on "sealover" (to the left of the arrow)

This will open the "sealover" profile page. The "Last 10 posts:" shows ten biogeochemistry related threads. Any of them can be opened with a click.
The first post on page 1 of this thread is by "sealover", to open profile page.

-----------------------------------------------------------

This thread really IS about the biogeochemistry of restoring alkalinity to the ocean, primarily through the action of sulfate reducing bacteria. As an example, a methane oxidizing sulfate reducing bacteria, under low oxygen conditions:

CH4 + SO4(2-) = H20 + H2S + CO3(2-)
Methane + sulfate = water + hydrogen sulfide + carbonate

versus

CH4 + 2O2 = 2H2O + CO2 for aerobic respiration or combustion
Methane + oxygen = water + carbon dioxide

Sulfate reduction by bacteria under low oxygen conditions is a very important biochemical process in nature.

In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

Anthropogenic CO2 emissions have increased the amount of carbon dioxide dissolved in sea water, consequently increasing the concentration of carbonic acid that forms from a fraction of 1% of the dissolved CO2. This carbonic acid is the source of the "acidification" in the term ocean acidification.

Through the pH buffering of the carbonate system in sea water, this increase in acid concentration has caused little change to the pH of the ocean. It has only decreased by about 0.1 pH unit, from about pH 8.3 to pH 8.2.

Of far greater consequence to marine life than the small pH change is the substantial change to the bioavailability of carbonate ion, CO3(2-), to form calcium carbonate shell. Commercial marine aquaculture must now purchase chemical carbonate to add to sea water in order for it to have enough for healthy larval shell development.

This thread includes scientific discussion of the biogeochemistry of alkalinity generation in coastal wetlands by microbial sulfate reduction.

Entering the sea primarily as submarine groundwater discharge, the carbonate ions and bicarbonate ions produced by microbial sulfate reduction are a counterbalance to the carbonic acid increase due to anthropogenic CO2.


"sealover" is a PhD biogeochemist who performed extensive groundwater chemistry investigations in the Sacramento-San Joaquin delta. This direct source of "submarine groundwater discharge" from the delta to the sea, and the biogeochemical mechanisms regulating its composition, is what I studied.

The most relevant posts of this thread are compiled, beginning very near the bottom of page 8, continuing through most of page 9
09-12-2024 20:23
Into the NightProfile picture★★★★★
(22820)
Im a BM wrote:
This thread really IS about the biogeochemistry of restoring alkalinity to the ocean, primarily through the action of sulfate reducing bacteria. As an example, a methane oxidizing sulfate reducing bacteria, under low oxygen conditions:

There is no such thing as 'biogeochemistry'. Buzzword fallacy.
Alkalinity is not a chemical. Sulfate is not a chemical. It can't be reduced.
Im a BM wrote:
In the absence of oxygen, sulfate reducing bacteria use sulfate, SO4(2-)- as oxidant to exploit organic carbon.

Sulfate is not a chemical. It is not an oxidizer. Carbon is not organic.
Im a BM wrote:
Carbonate ions and bicarbonate ions created by microbial sulfate reduction are the major source of ALKALINITY for many marine ecosystems.

Alkalinity is not a chemical. Sulfate is not a chemical Carbonate is not a chemical. Bicarbonate is not a chemical. Buzzword fallacies.
Im a BM wrote:
Anthropogenic CO2 emissions have increased the amount of carbon dioxide dissolved in sea water, consequently increasing the concentration of carbonic acid that forms from a fraction of 1% of the dissolved CO2. This carbonic acid is the source of the "acidification" in the term ocean acidification.

CO2 has no identifier. You can't acidify an alkaline.
Im a BM wrote:
Through the pH buffering of the carbonate system in sea water, this increase in acid concentration has caused little change to the pH of the ocean. It has only decreased by about 0.1 pH unit, from about pH 8.3 to pH 8.2.

It is not possible to measure the pH of the ocean.
Im a BM wrote:
Of far greater consequence to marine life than the small pH change is the substantial change to the bioavailability of carbonate ion, CO3(2-), to form calcium carbonate shell. Commercial marine aquaculture must now purchase chemical carbonate to add to sea water in order for it to have enough for healthy larval shell development.

Carbonate is not a chemical. You can't purchase it.
Im a BM wrote:
This thread includes scientific discussion of the biogeochemistry of alkalinity generation in coastal wetlands by microbial sulfate reduction.

Biogeochemistry is a buzzword. Alkalinity is not a chemical. Sulfate is not a chemical. It cannot be reduced.
Im a BM wrote:
Entering the sea primarily as submarine groundwater discharge, the carbonate ions and bicarbonate ions produced by microbial sulfate reduction are a counterbalance to the carbonic acid increase due to anthropogenic CO2.

Carbonate is not a chemical. Bicarbonate is not a chemical. Sulfate is not a chemical. CO2 has no identifier.
Im a BM wrote:
"sealover" is a PhD biogeochemist

Buzzword fallacy. No such thing.
Im a BM wrote:
who performed extensive groundwater chemistry investigations in the Sacramento-San Joaquin delta. This direct source of "submarine groundwater discharge" from the delta to the sea, and the biogeochemical mechanisms regulating its composition, is what I studied.

No such thing as 'biogeochemical'. Buzzword fallacy. You deny and discard chemistry. Stop pretending to be a chemist.
Im a BM wrote:

The most relevant posts of this thread are compiled, beginning very near the bottom of page 8, continuing through most of page 9


Stop spamming.


The Parrot Killer

Debunked in my sig. - tmiddles

Google keeps track of paranoid talk and i'm not on their list. I've been evaluated and certified. - keepit

nuclear powered ships do not require nuclear fuel. - Swan

While it is true that fossils do not burn it is also true that fossil fuels burn very well - Swan
11-01-2025 21:48
Im a BM
★★★★☆
(1622)
Let us use one liter of pure water as a microcosm for a vast reservoir of pure water.

Let us perform an experiment on one liter of pure water that represents the addition of 150 gallons of concentrated hydrochloric acid, 11.6 Molar, to a reservoir of pure water 500 meters wide, 600 meters long, and 20 meters deep.

The big reservoir contains six million cubic meters, or 6000 million LITERS.

We want one sixth BILLIONTH to be represented in our one liter test, so we add one six billionth the amount of acid contained in 150 gallons of the strong stuff.

Presto chango, we can have fun comparing the math and...

One drop of acid containing 1/6,000,000,000 the H+ in 150 gallons into one liter of pure water and the pH is...

5.96

Prove me wrong, science man!

Then I'll show you how real scientists calculate chemicals and stuff and you will see how one drop of acid makes a liter of pure water drop by more than one whole pH unit. An order of magnitude more acidic than before.

One drop of that same acid into one liter of SEA WATER.

Let's predict how much "more pronounced" the impact will be. How much larger the change to how much hydrogen ion is solution will be. Well, it certainly isn't going to be MORE BUFFERED against pH change than pure water, cause it don't got no more room than pure water to DILUTE it. Dilution is buffering, moron.

I'll show you my math so you can call me a moron.



The birth of a respectful and productive discussion about ocean acidification.

From March 10, 2022 - Within hours of very first "sealover" post.

The assertions that "sealover" made regarding sea water chemistry were immediately challenged.

My stupidity for suggesting that a liter of pure water, with virtually no pH buffering capacity (i.e. alkalinity), would show a much greater pH decrease upon addition of a drop of acid, compared to a liter of sea water, was mocked.

No, that was NOT the answer, says IBdaMann, most respectfully.

The CORRECT answer is that:

"The impact of a drop of acid would be more pronounced on the sea water than on the pure water." - IBdaMann


So, within hours of my first post, in March 2022, the first "debate" about a chemistry point of fact.

Well, this should be easy to clear up, you would think.

OF COURSE sea water is more buffered against pH change than pure water.

That's easy enough to prove to any scientifically literate rational adult, right?

Well, it turns out that it's NOT so easy to prove such a simple point of science to a scientifically illiterate troll.

Two and a half years later, the rebuttal to this first "Mr. Chemistry Genius" claim I made about pure water having virtually no pH buffering capacity CONTINUES.

NO! NO! NO! Water itself is a buffer for acid, they continue to say.

And don't forget that an acid would have to be "magical" to have pH equal zero.

Didn't really get to take the biogeochemistry to very sophisticated level in this particular discussion.

Still can't agree what a buffer is or even how pH works.

Sigh.

IBdaMann wrote:
sealover wrote:If I take a liter of pure water and add just one drop of concentrated acid, I will see a huge drop in pH.

So, Mr. Chemistry Genius, the correct answer is that if you were to get your hands on some magical acid whose pH is 0.0, and you were to add one single drop to one liter/litre of pure water (pH 7.0) and one single drop to one liter/litre of sea water (pH 8.4), the impact of a drop of the acid would be more pronounced on the sea water than on the pure water.

Do the math.

sealover wrote: Remember, this thread is about restoring "alkalinity" to the sea.

That's like restoring white to snow. It's already there. Just go out and claim victory!

sealover wrote:Alkalinity is another word for acid neutralizing capacity.

Great circular definition ... and acidity is another word for alkaline neutralizing capacity.

Acidity is the ability to provide a hydrogen ion. Alkalinity is the ability to accept a hydrogen ion.

sealover wrote:The alkalinity of pure water arises entirely from hydroxide ions.

Do you see what I mean? Only a scientifically illiterate moron would refer to the alkalinity of pure water. Next, you'll be talking about the temperature of deep space.

sealover wrote:The overwhelming majority of the alkalinity in sea water arises from bicarbonate and carbonate ions.

Let's not forget hydroxide, silicates and phosphates. They're people too.

sealover wrote:A 30% depletion of the ocean's alkalinity has resulted in only a small decrease in pH.

That's just one number so I can see how you could so easily pull that out of your arsewhole. I think it explains the stink quite nicely.

sealover wrote:On the other hand, it has caused a HUGE change to the bioavailability of carbonate ion.

The "bioavailability"? Don't you mean the "ecolobiquity"? ... or maybe the "presenvironance"?
Page 16 of 16<<<141516





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